Condensation is an important research topic that ensures increased energy efficiency. Our researchers aimed to optimize heat transfer in industrial heat exchanger tubes through surface modification. We first succeeded in fabricating superhydrophilic and superhydrophobic tubes using surface modification. We observed the condensation phenomenon on the outside of the tube and evaluated the heat transfer performance through a condensation experimental facility. As a result, we found that the condensation heat transfer efficiency of superhydrophobic tubes is superior to that of conventional tubes. However, the heat transfer efficiency of the superhydrophobic tube reduced with an increase in saturation. To improve performance degradation, superhydrophilic and superhydrophobic hybrid tubes were fabricated and evaluated for their potential to improve heat transfer efficiency. As a result, we found that the liquid film generated by filmwise condensation on the superhydrophilic surface swept past the residual droplets generated by dropwise condensation on the superhydrophobic surface, resulting in the best heat transfer performance. Our results break the stereotypes of previous studies and provide a new paradigm for achieving optimal heat transfer performance on large-area curved surfaces. This research is expected to be widely applied in a variety of industries where energy efficiency is critical.