Degradation of proton exchange membrane fuel cells (PEMFCs) can be accelerated by impurities in the air. In maritime environments in particular, sodium chloride (NaCl) can reduce the performance of membrane electrode assembly (MEA) in PEMFCs. In this context, we experimentally analyzed effect of flow channel depth on PEMFCs humidified with a NaCl solution at the cathode side. The analysis was conducted in serpentine flow channels with different depths of 0.4, 0.8, and 1.6 mm. The initial performance of unit cells was compared to their performance after applying a constant current for 10 hours. Results showed that the degradation rate correlated positively with the flow-channel depth. Channel depths of 0.4 and 1.6 mm resulted in 2.4% and 7.3% decreases in the maximum power density, respectively. For the 1.6 mm channel depth, the activation loss after 10 hours was larger than the initial loss.
Durability evaluations were conducted using polymer electrolyte membrane fuel cells in a marine environment. Deionised water and 3.5 wt% of NaCl solution were supplied to the cathode using an ultrasonic vibrator. Performance and electrochemical impedance spectroscopy of fuel cells were measured to evaluate the electrochemical behaviors. Additionally, long-term stability evaluations of PEMFCs were carried out at 0.65 V for 20 h. Following the experiments, scanning electron microscope analysis was conducted to confirm the presence of NaCl on membrane electrode assembly and micro porous layer of fuel cells.
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In this study, polymer electrolyte membrane fuel cells (PEMFCs) were humidified with NaCl solutions. NaCl solutions were provided to the cathode side of fuel cells by bubbling. De-Ionized water, 3.5 wt% NaCl solution, and 20 wt% NaCl solution were used to evaluate the effects of NaCl. Current density-voltage curves and electrochemical impedance spectroscopies (EIS) of fuel cells were measured. Additionally, the constant-voltage mode long-term stability of PEMFCs humidified with NaCl solution were investigated. Constant-voltage measurements and EIS results imply that the degradation of fuel cells is clearly related with the concentration of NaCl solutions.
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Effects of NaCl Solution on Proton Exchange Membrane Fuel Cell with Serpentine Flow Channel of Different Depths Dong Kun Song, Ho Jun Yoo, Jung Soo Kim, Ki Won Hong, Do Young Jung, George Ilhwan Park, Gu Young Cho Journal of the Korean Society for Precision Engineering.2025; 42(5): 399. CrossRef
Analysis of Electrochemical Behavior of PEMFC Humidified with NaCl Solution Mist Using an Ultrasonic Vibrator Ho Jun Yoo, Gye Eun Jang, Young Jo Lee, Dong Kun Song, Heeyun Lee, Gu Young Cho Journal of the Korean Society for Precision Engineering.2022; 39(12): 939. CrossRef