This paper presents a construction method regarding a tubular nano-mesh for which the anodic oxidation of aluminum (Al) wire is used. The first step of tubular-nano-mesh production is Al-wire anodization. A new anodizing device was made for the wire-based uniform anodization for this study, and a high-purity (99.999%) Al wire with a 2 mm diameter was used. Also, an electrolytic solution was used as a 0.07 M oxalic acid, while the electrolytic-solution temperature was maintained at -3℃. While the applied voltage and the process time were varied, the AAO (Anodic Aluminum Oxide) characteristics of the Al wire were observed. When 60 V was applied to the wire, alumina cracks were not evident, whereas the application of 100 V produced alumina cracks; this is because the growth rate of the nano-pore voltage affected the alumina shape. For the subsequent construction of the tubular alumina structure, an Al-etchant (HCl + H2O + CuCl2 + 2H2O) etched-Al portion of the anodized wire was employed. The final step is a pore-widening process that is implemented through the hole channel. The anodized wire was dipped in the alumina etchant, and the pore-wall removal was checked over time.
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Effect of Nanochannel Size of Surface Treated Thru-Hole Alumina Membrane in Rejection of Polar Molecules Eui Don Han, Byeong Hee Kim, Young Ho Seo International Journal of Precision Engineering and Manufacturing.2018; 19(2): 287. CrossRef