All-solid-state batteries (ASSBs) utilizing non-flammable inorganic electrolytes are gaining significant attention due to safety concerns associated with conventional lithium-ion batteries. Among various oxide electrolytes, lithium lanthanum titanate (LLTO) demonstrates high ionic conductivity at room temperature but is prone to lithium loss at elevated sintering temperatures. In this study, we employed electrostatic spray deposition (ESD) at 250℃, followed by flash light sintering within milliseconds using a xenon lamp. This approach enabled the production of dense and highly crystalline LLTO thin films with minimal lithium evaporation. Scanning electron microscopy (SEM) analysis confirmed reduced porosity at 650V, while X-ray photoelectron spectroscopy (XPS) revealed stable lithium content. Additionally, X-ray diffraction (XRD) indicated the formation of a cubic perovskite structure that is beneficial for ionic transport. This rapid and scalable process shows promise for producing high-quality LLTO electrolytes, thereby enhancing the safety and performance of next-generation ASSBs.

In this study, we introduce a novel flash light sintering (FLS) method to address the issue of secondary phase formation in conventional high-temperature thermal sintering processes. The microstructure and cross section of the Lanthanum strontium cobalt (LSC) air electrode were analyzed using field emission scanning electron microscopy (FE-SEM). The presence of secondary phases was evaluated using X-ray diffraction (XRD) and energy-dispersive spectroscopy (EDS) in SEM. Electrochemical performance was assessed using NiO-YSZ anode-supported LSC cathode cells at 750oC. The maximum power density of the thermally sintered LSC cathode at 900oC was 272.4 mW/cm², while the flash light sintered LSC cathode by 18.5 J/cm² achieved 2,222 mW/cm². These results demonstrate that the flash light sintering process can effectively prevent secondary phase formation and successfully sinter the electrode, thereby enhancing the performance and reliability of SOFCs.

A high temperature sintering process for solid electrolyte is the main cause of the increase in manufacturing costs of SOFCs. In this study, we developed a novel flash light sintering technique as an alternative sintering process of the conventional thermal sintering process. The YSZ electrolyte films were fabricated by conventional screen-printing method and the flash light sintering process and ESB sintering aid were applied to improve the flash light sinterability of the YSZ electrolyte. In the flash light sintering process, the effect of various pulse conditions such as energy density, and pulse interval were investigated and the microstructure, crystallinity, and sintering behavior of the sintered films were analyzed to demonstrate the effectiveness of the flash light sintering process. The flash light sintered YSZ electrolyte layer was used to fabricate the anode-supported SOFCs and its functionality is successfully demonstrated with the high open circuit voltage. The significance of this study includes minimization of the process time from tens of hours to just a few seconds, thus facilitating the commercialization of SOFCs.