A chemical ablation analysis of hypersonic missile for thermal protection design was performed using SAMCEF AMARYLLIS V.17, the specific ablation module of commercial software based on a finite element code. The pyrolysis and surface recession models based on the effects of mass loss, pore gas diffusion, and endothermic reaction energy were applied for non-linearity of material and boundary. The numerical studies were carried out to confirm the tendency of the pyrolysis and chemical ablation of theoretical ablative composite for open testing (TACOT) with a chemical composition similar to charring carbon/phenolic composites. The frequency of variation in surface recession, temperature, density and gas mass flux was reviewed to determine the characteristics of multiple decomposition reactions and oxidation via pyrolysis of gas species.